High-Performance Organic Solar Cells with Efficient Semiconducting Small Molecules Containing an Electron-Rich Benzodithiophene Derivative
- Authors
- Lim, Namwoo; Cho, Nara; Paek, Sanghyun; Kim, Chulwoo; Lee, Jae Kwan; Ko, Jaejung
- Issue Date
- 8-4월-2014
- Publisher
- AMER CHEMICAL SOC
- Citation
- CHEMISTRY OF MATERIALS, v.26, no.7, pp.2283 - 2288
- Indexed
- SCIE
SCOPUS
- Journal Title
- CHEMISTRY OF MATERIALS
- Volume
- 26
- Number
- 7
- Start Page
- 2283
- End Page
- 2288
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/98777
- DOI
- 10.1021/cm5004092
- ISSN
- 0897-4756
- Abstract
- High-performance organic semiconductors based on an electron-rich alkylsilylethynyl benzodithiophene (TIPSBDT) core were newly synthesized and characterized for use in solution-processed small-molecule organic solar cells. The rigid and extended if-conjugation of the TIPSBDT motifs facilitates intramolecular charge transfer and intermolecular pi-pi packing interactions of semiconducting small molecules in the BHJ film enhanced by processing additives and induces deep HOMO levels producing high open-circuit voltage of similar to 1.0 V, exhibiting notable power conversion efficiency of 5.84% from a bulk-heterojunction film with PC61BM.
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Collections - College of Science and Technology > Department of Advanced Materials Chemistry > 1. Journal Articles
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