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Synthesis of 2-Aminoquinoxalines via One-Pot Cyanide-Based Sequential Reaction under Aerobic Oxidation Conditions
- Authors
- Cho, Yeon-Ho; Kim, Kyung-Hee; Cheon, Cheol-Hong
- Issue Date
- 7-2월-2014
- Publisher
- AMER CHEMICAL SOC
- Citation
- JOURNAL OF ORGANIC CHEMISTRY, v.79, no.3, pp.901 - 907
- Indexed
- SCIE
SCOPUS
- Journal Title
- JOURNAL OF ORGANIC CHEMISTRY
- Volume
- 79
- Number
- 3
- Start Page
- 901
- End Page
- 907
- ISSN
- 0022-3263
- Abstract
- A highly efficient synthesis of 2-aminoquinoxalines has been developed via the one-pot two-step cyanide-mediated sequential reactions of ortho-phenylenediamines with aldehydes under aerobic oxidation conditions. A variety of substrates, including aliphatic aldehydes bearing acidic a-protons, are applicable to this protocol and afford the desired 2-aminoquinoxalines in high yields.
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