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New iridium complexes with two pre-organized urea groups and thiourea groups as phosphorescent chemosensors for H2PO4- and chiral carboxylates
- Issue Date
- Jan-2014
- Publisher
- ELSEVIER SCI LTD
- Keywords
- Phosphorescence chemosensor; Anion recognition; Dihydrogen phosphate sensing; Chiral recognition; Iridium complex; Amino acid sensing
- Citation
- DYES AND PIGMENTS, v.100, pp.241 - 246
- Indexed
- SCIE
SCOPUS
- Journal Title
- DYES AND PIGMENTS
- Volume
- 100
- Start Page
- 241
- End Page
- 246
- ISSN
- 0143-7208
- Abstract
- As a versatile platform for phosphorescent chemosensors, bis(benzylic amine) derivative 6 was synthesized. Two urea groups could be readily introduced for phosphorescent chemosensor 1. A preorganized binding pocket could induce a selective phosphorescence enhancement with H2PO4-. A new iridium complex 2 bearing two thiourea groups as well as glucopyranosyl chiral barriers is reported as a first chiral phosphorescent chemosensor for amino acids. (C) 2013 Elsevier Ltd. All rights reserved.
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Related Researcher
- Park, Sung nam
- College of Science (Department of Chemistry)