Detailed Information
Cited 0 time in 
Cited 0 time in 
Cited 0 time in
Metadata Downloads
Synthesis and Structural Characterization of Hexacoordinate Silicon, Germanium, and Titanium Complexes of the E-coli Siderophore Enterobactin
- Authors
- Baramov, Todor; Keijzer, Karlijn; Irran, Elisabeth; Moesker, Eva; Baik, Mu-Hyun; Suessmuth, Roderich
- Issue Date
- 5-8월-2013
- Publisher
- WILEY-V C H VERLAG GMBH
- Keywords
- enterobactin; germanium; siderophores; silicon; titanium
- Citation
- CHEMISTRY-A EUROPEAN JOURNAL, v.19, no.32, pp.10536 - 10542
- Indexed
- SCIE
SCOPUS
- Journal Title
- CHEMISTRY-A EUROPEAN JOURNAL
- Volume
- 19
- Number
- 32
- Start Page
- 10536
- End Page
- 10542
- ISSN
- 0947-6539
- Abstract
- The E. coli siderophore enterobactin, one of the strongest Fe-III chelators known to date, is also capable of binding Si-IV under physiological conditions. We report on the synthesis and structural characterization of the tris(catecholate) Si-IV-enterobactin complex and its Ge-IV and Ti-IV analogues. Comparative structural analysis, supported by quantum-chemical calculations, reveals the correlation between the ionic radius and the structural changes in enterobactin upon complexation.
- Files in This Item
- There are no files associated with this item.
- Appears in
Collections - Graduate School > Department of Material Chemistry > 1. Journal Articles
Items in ScholarWorks are protected by copyright, with all rights reserved, unless otherwise indicated.