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Photo-induced cation exchange reaction of germanium chalcogenide nanocrystals synthesized using gas-phase laser photolysis reaction

Authors
Myung, YoonIm, Hyung SoonKim, Chang HyunJung, Chan SuCho, Yong JaeJang, Dong MyungKim, Han SungBack, Seung HyukPark, Jeunghee
Issue Date
2013
Publisher
ROYAL SOC CHEMISTRY
Citation
CHEMICAL COMMUNICATIONS, v.49, no.2, pp.187 - 189
Indexed
SCIE
SCOPUS
Journal Title
CHEMICAL COMMUNICATIONS
Volume
49
Number
2
Start Page
187
End Page
189
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/106517
DOI
10.1039/c2cc37513c
ISSN
1359-7345
Abstract
Germanium chalcogenide GeSxSe1-x nanocrystals (NC) were synthesized using a novel gas-phase laser photolysis reaction. The composition was simply controlled by the partial pressure of precursors in a closed reactor. Remarkably, these ligand-free NC undergo the photoinduced cation exchange reaction to produce a series of Cd, Zn, Pb, and Ag chalcogenide NC in aqueous solution, which is governed by the thermodynamic driving force based on solubility.
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