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Fabrication of 1 μm thickness lead zirconium titanate films using poly(N-vinylpyrrolidone) added sol-gel method

Authors
Oh, S.M.Kang, M.-G.Do, Y.H.Kang, C.Y.Yoon, S.J.Nahm, S.
Issue Date
2011
Publisher
Korean Institute of Electrical and Electronic Material Engineers
Keywords
Lead zirconate titanate; Poly(vinylpyrrolidone); Sol-gel; Thickness control
Citation
Transactions on Electrical and Electronic Materials, v.12, no.5, pp.222 - 225
Indexed
SCOPUS
KCI
Journal Title
Transactions on Electrical and Electronic Materials
Volume
12
Number
5
Start Page
222
End Page
225
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/114601
DOI
10.4313/TEEM.2011.12.5.222
ISSN
1229-7607
Abstract
Lead zirconate titanate (PZT) films were fabricated on Pt/Ti/SiO<inf>2</inf>/Si substrate by the sol-gel method using a sol containing poly(N-vinylpyrrolidone) (PVP). PVP in alkoxide solutions can suppress the condensation reaction in gel films during heat treatment, and increase the viscosity of alkoxide solutions. Single-phase PZT films as thick as 1 μm were deposited by repetitive coating with successive third-step heat treatments at 150°C, 350°C and 650°C;. After heat treatment, the films were crack free, and optically transparent. As a result, we demonstrated a PZT film with a PVP molar ratio of 0.5, which has a permittivity of 734, a dielectric loss of 0.042, a P<inf>r</inf> of 40.5 μC/cm2 and an E<inf>c</inf> of 156 kV/cm. © 2011 KIEEME. All rights reserved.
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