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Electrical Properties of Bi2Ti2O7 Thin Films Grown at Low Temperature by the Pulsed Laser Deposition

Authors
Kang, Lee-SeungKim, Jin-SeongSun, Jong-WooKweon, Sang-HyoSong, Myung-EunPaik, Dong-SooSung, Tae-HyunNahm, Sahn
Issue Date
2011
Publisher
ELECTROCHEMICAL SOC INC
Citation
ELECTROCHEMICAL AND SOLID STATE LETTERS, v.14, no.6, pp.G38 - G41
Indexed
SCIE
SCOPUS
Journal Title
ELECTROCHEMICAL AND SOLID STATE LETTERS
Volume
14
Number
6
Start Page
G38
End Page
G41
URI
https://scholar.korea.ac.kr/handle/2021.sw.korea/114908
DOI
10.1149/1.3564877
ISSN
1099-0062
Abstract
A crystalline Bi2Ti2O7 (B2T2) film with a high dielectric constant (epsilon(r)) of 67.2 was formed even at 300 degrees C when the oxygen pressure (OP) exceeded 600 mTorr, even though the Bi4Ti3O12 target was used. The Mn-doping improved the electrical properties of the B2T2 films by producing the doubly ionized, extrinsic oxygen vacancies, which reduced the number of intrinsic oxygen vacancies. The B2T2 film containing 20 mol% of Mn ions, which was annealed under an OP of 75.0 Torr, exhibited a low leakage current density of 5 x 10(-7) A/cm(2) at 0.5 MV/cm(2) and a large epsilon(r) (similar to 73) with a low tan delta (similar to 1.3%). (C) 2011 The Electrochemical Society. [DOI: 10.1149/1.3564877] All rights reserved.
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