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Charge-compensated Zn metallocenes with sigma-/pi-chelating carboranyl ligands for the formation of constrained geometry Ru(II) and Ni(II) complexes
- Issue Date
- 2011
- Publisher
- ROYAL SOC CHEMISTRY
- Citation
- CHEMICAL COMMUNICATIONS, v.47, no.3, pp.1018 - 1020
- Indexed
- SCIE
SCOPUS
- Journal Title
- CHEMICAL COMMUNICATIONS
- Volume
- 47
- Number
- 3
- Start Page
- 1018
- End Page
- 1020
- ISSN
- 1359-7345
- Abstract
- Charge-compensated zinc metallocenes of types [(eta(3)-C2B9H10)(2)Zn]-[(eta(1)-NMe2)ZnEt](2) (5) and [{eta(3)-(Me)C2B9H9}(2)Zn][(eta(1)-NMe2)-ZnEt](2) (6) were produced by reacting sigma-/pi-chelating aminoalkyl dicarbollides, 7-Me2N(H)CH2-7,8-C2B9H11 (1) and 7-Me2N(H)CH2-8-Me-7,8-C2B9H10 (2), with diethylzinc. Zincocene 5 proved to be an excellent synthon for the formation of dicarbollide-based sigma-/pi-type constrained Ru and Ni complexes.
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Collections - Graduate School > Department of Advanced Materials Chemistry > 1. Journal Articles
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