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An iron(II) complex with a N3S2 thioether ligand in the generation of an iron(IV)-oxo complex and its reactivity in olefin epoxidation
- Authors
- Annaraj, Jamespandi; Kim, Soohee; Seo, Mi Sook; Lee, Yong-Min; Kim, Youngmee; Kim, Sung-Jin; Choi, Young S.; Jang, Ho G.; Nam, Wonwoo
- Issue Date
- 20-2월-2009
- Publisher
- ELSEVIER SCIENCE SA
- Keywords
- Oxygen activation; Nonheme iron enzymes; Biomimetics; High-valent iron-oxo intermediate; Epoxidation
- Citation
- INORGANICA CHIMICA ACTA, v.362, no.3, pp.1031 - 1034
- Indexed
- SCIE
SCOPUS
- Journal Title
- INORGANICA CHIMICA ACTA
- Volume
- 362
- Number
- 3
- Start Page
- 1031
- End Page
- 1034
- ISSN
- 0020-1693
- Abstract
- A new iron(II) complex bearing an N3S2 thioether ligand was synthesized and characterized with various spectroscopic techniques and X-ray crystallography. A mononuclear nonheme iron(IV)-oxo intermediate was generated in the reaction of the iron(II) complex with various terminal oxidants. Theiron (IV)-oxo species show a capability of epoxidizing olefins, and the olefin epoxidation occurs via an electrophilic oxidation mechanism. (C) 2008 Elsevier B.V. All rights reserved.
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