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Intermolecular Contact-Tuned Magnetic Nature in One-Dimensional 3d-5d Bimetallic Systems: From a Metamagnet to a Single-Chain Magnet
- Authors
- Choi, Seok Woo; Kwak, Hyun Young; Yoon, Jung Hee; Kim, Hyoung Chan; Koh, Eui Kwan; Hong, Chang Seop
- Issue Date
- 17-11월-2008
- Publisher
- AMER CHEMICAL SOC
- Citation
- INORGANIC CHEMISTRY, v.47, no.22, pp.10214 - 10216
- Indexed
- SCIE
SCOPUS
- Journal Title
- INORGANIC CHEMISTRY
- Volume
- 47
- Number
- 22
- Start Page
- 10214
- End Page
- 10216
- ISSN
- 0020-1669
- Abstract
- Assembling [W(CN)(6)(bpy)](-) and magnetic anisotropic Mn Schiff bases produced two Mn-III(3d)-W-V(5d) bimetallic chains. Modulation of the types and degrees of interchain pi-pi interactions in the one-dimensional coordination polymers leads to the variation of the magnetic behavior from a metamagnetic character to a single-chain magnet property.
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