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New Types of o-Carborane-Based Chiral Phosphinooxazoline (Cab-PHOX) Ligand Systems: Synthesis and Characterization of Chiral Cab-PHOX Ligands and Their Application to Asymmetric Hydrogenation
- Issue Date
- 17-Mar-2009
- Publisher
- GEORG THIEME VERLAG KG
- Keywords
- chiral phosphinooxazoline ligands; o-carborane-based bidentate ligands; asymmetric hydrogenation; unfunctionalized olefins; functionalized olefins
- Citation
- SYNLETT, no.5, pp.771 - 774
- Indexed
- SCIE
SCOPUS
- Journal Title
- SYNLETT
- Number
- 5
- Start Page
- 771
- End Page
- 774
- ISSN
- 0936-5214
- Abstract
- o-Carborane-based chiral phosphinooxazoline (Cab-PHOX) ligands were synthesized for the first time and applied to the iridium and rhodium-catalyzed hydrogenation of unfunctionalized and functionalized olefins with an enantioselectivity of up to 98% and 96%, respectively. The modularity of the Cab-PHOX ligands is highlighted by the facile preparation of a variety of sterically and electronically different ligands.
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Collections - Graduate School > Department of Advanced Materials Chemistry > 1. Journal Articles
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