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New types of charge-compensated metallacarboranes: Synthesis, characterization, and structural studies of [(eta(5)-RC2B9H9CH2NMe2) Cr(mu-Cl)Cl](2) (R = H, Me)
- Authors
- Kang, Sang Ook; Lee, Jong-Dae
- Issue Date
- 1-12월-2015
- Publisher
- ELSEVIER SCIENCE SA
- Keywords
- Metallacarborane; Charge-compensated metal complexes; Chromium; Hydrogen bond; X-ray crystallography
- Citation
- JOURNAL OF ORGANOMETALLIC CHEMISTRY, v.798, pp.121 - 124
- Indexed
- SCIE
SCOPUS
- Journal Title
- JOURNAL OF ORGANOMETALLIC CHEMISTRY
- Volume
- 798
- Start Page
- 121
- End Page
- 124
- ISSN
- 0022-328X
- Abstract
- Charge-compensated dicarbollyl chromium complexes of the type [(eta(5)-RC2B9H9 CH2NMe2)Cr(mu-Cl)Cl](2) (R = 5 and Me 6) were produced by reacting dicarbollylamino aluminum compounds [(mu(5)-RC2B9H9)(eta(1)-CH2NMe2)AlMe] with CrCl3 center dot THF3 in toluene solvent. This new complex is a relatively rare example of a dicarbollylchromium(III) complex containing unpaired electrons. An X-ray crystallographic investigation of 6 reveals a three-legged piano stool structure with a planar dichromium Cr unit containing bridged chloride ions. (C) 2015 Elsevier B.V. All rights reserved.
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