Mechanistic Insights into Thermal Stability Improvement of exo-Tetrahydrodicyclopentadiene by a New Hydrogen Donor: 5,6,7,8-Tetrafluoro-1,2,3,4-tetrahydroquinoxaline
- Authors
- Park, Sun Hee; Park, Yumi; Han, Jeong Sik; Jeong, Byung Hun; Han, Hogyu; Kim, Sung Hyun
- Issue Date
- 1월-2015
- Publisher
- AMER CHEMICAL SOC
- Citation
- ENERGY & FUELS, v.29, no.1, pp.16 - 20
- Indexed
- SCIE
SCOPUS
- Journal Title
- ENERGY & FUELS
- Volume
- 29
- Number
- 1
- Start Page
- 16
- End Page
- 20
- URI
- https://scholar.korea.ac.kr/handle/2021.sw.korea/94732
- DOI
- 10.1021/ef5016445
- ISSN
- 0887-0624
- Abstract
- We investigated the thermal stability of exo-tetrahydrodicyclopentadiene (exo-THDCP, C10H16) in the absence and presence of 5,6,7,8-tetrafluoro-1,2,3,4-tetrahydroquinoxaline (TFQox), a new hydrogen donor (H donor). Conversion of exo-THDCP was slowed in the presence of TFQox but less effectively compared to its analogues, 1,2,3,4-tetrahydroquinoxaline (THQox) and 1,2,3,4-tetrahydroquinoline (THQ). We analyzed the H-donor effects on the thermal decomposition kinetics of exo-THDCP, which explains the relative effect of the H donors on the thermal stability improvement of exo-THDCP.
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Collections - College of Science > College of Science > 1. Journal Articles
- College of Engineering > Department of Chemical and Biological Engineering > 1. Journal Articles
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